A putative mechanism for capture of carbon dioxide by quartz, mediated by triboelectric charging

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چکیده

Mechanical activation of quartz grains in a dry atmosphere causes triboelectric charging that can capture CO2 quantitatively (Thøgersen et al., https://doi.org/10.1016/j.cplett.2021.139069). Based on electron structure calculations, we propose mechanism for this process. According to the mechanism, is inserted lattice form an anchored CO3 moiety. Predicted 13C chemical shifts product agree with solid-state NMR measurements.

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ژورنال

عنوان ژورنال: Chemical Physics Letters

سال: 2023

ISSN: ['0009-2614', '1873-4448']

DOI: https://doi.org/10.1016/j.cplett.2023.140395